Information om | Engelska ordet HYDROSILYLATION

Exempel på hur man kan använda HYDROSILYLATION i en mening

• Complexes derived from non-coordinating anions have been used to catalyze hydrogenation, hydrosilylation, oligomerization, and the living polymerization of alkenes.
• The Reduction of gold, cobalt, nickel, palladium, or platinum organometallic complexes with silanes produces metal nanoparticle that catalyze the hydrosilylation reaction.
• In certain cases, hydrosilylation results in vinyl or allylic silanes resulting from beta-hydride elimination.
• Dendrimers with peripheral ferrocene groups are usually synthesized by attaching ferrocene to the core by either olefin metathesis or by hydrosilylation.
• Pincer ligands participate in a variety of organic transformation, such as the hydrosilylation, and ethylene oligomerizations, and homocoupling of benzyl halides.
• Asymmetric hydrosilylation of ketones to chiral secondary alcohols with good yields and excellent enantioselectivities using Cu-Al hydrotalcite and BINAP has opened up a new perspective.
• Rather than polymerization, the alkene group can undergo a hydrosilylation reaction with siloxanes in the presence of chloroplatinic acid as catalyst.
• Evaluation of effectiveness of Fe(0) complexes with multivinylsilicone ligands in hydrosilylation and dehydrogenative silylation of styrene with trisubstituted silanes and hydrosiloxanes.
• Studies have shown that organolanthanides are extraordinary catalysts for hydrofunctionalization reactions including hydrogenation, hydrosilylation, hydroboration, hydroamination, etc.
• He was a prolific researcher in the development of new synthetic methods based on transition-metal catalyzed reactions and investigations into their mechanisms, which includes hydrosilylation, silylformylation, silylcarbocyclizations (SiCaCs, SiCaB, SiCaT), higher order (carbonylative) cycloadditions, hydroformylation, hydrocarbonylations, amidocarbonylations, cyclohydrocarbonylations, and enantioselective processes such as hydrosilylation, hydrogenation, hydroformylation, Michael addition, allylic alkylation/amination/etherification, etc.
• The regioselectivity and stereoselectivity of hydrosilylation of 1-methylcyclohexene with chloro(methyl)silanes depends on the number of chlorine atoms in the hydrosilylating agent.

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