Synonymer & Anagram | Engelska ordet NITRENE

Exempel på hur man kan använda NITRENE i en mening

• The simplest nitrene, HN, is called imidogen, and that term is sometimes used as a synonym for the nitrene class.
• In addition to improving the existing functions of natural enzymes, Arnold has discovered enzymes that perform functions for which no previous specific enzyme existed, such as when she evolved cytochrome P450 to carry out cyclopropanation and carbene and nitrene transfer reactions.
• A nitrogen bound to both a good electrofuge and a good nucleofuge is known as a nitrenoid (for its resemblance to a nitrene).
• Known sulfonyl nitrenes include methyl sulfonyl nitrene, trifluoromethyl sulfonyl nitrene, and tolyl sulfonyl nitrene.
• Faul introduced multiple new wrinkles into this chemistry, including using chiral copper(I) catalysts to produce enantiomerically-enriched aziridines, and using a variety of different nitrene sources for the transfer.
• In 2012, his group published rhodium catalyzed intermolecular amidation of arenes using sulfonyl azide as a nitrene precursor.
• The reaction of a sulfinyl nitrene with sulfoxides results in a sulfonyl sulfoximde, with the oxygen joining the sulfinyl sulfur and its bond replaced by a double bond to nitrogen.

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